State functions Maxwell Relations
Tags: #physics #thermodynamicsEquation
$$\left(\frac{\partial T}{\partial V}\right)_{S}=-\left(\frac{\partial p}{\partial S}\right)_{V}~,~~\left(\frac{\partial T}{\partial p}\right)_{S}=\left(\frac{\partial V}{\partial S}\right)_{p}~,~~ \left(\frac{\partial p}{\partial T}\right)_{V}=\left(\frac{\partial S}{\partial V}\right)_{T}~,~~\left(\frac{\partial V}{\partial T}\right)_{p}=-\left(\frac{\partial S}{\partial p}\right)_{T} \\ TdS=C_VdT+T\left(\frac{\partial p}{\partial T}\right)_{V}dV~~\mbox{and}~~TdS=C_pdT-T\left(\frac{\partial V}{\partial T}\right)_{p}dp$$Latex Code
\left(\frac{\partial T}{\partial V}\right)_{S}=-\left(\frac{\partial p}{\partial S}\right)_{V}~,~~\left(\frac{\partial T}{\partial p}\right)_{S}=\left(\frac{\partial V}{\partial S}\right)_{p}~,~~ \left(\frac{\partial p}{\partial T}\right)_{V}=\left(\frac{\partial S}{\partial V}\right)_{T}~,~~\left(\frac{\partial V}{\partial T}\right)_{p}=-\left(\frac{\partial S}{\partial p}\right)_{T} \\ TdS=C_VdT+T\left(\frac{\partial p}{\partial T}\right)_{V}dV~~\mbox{and}~~TdS=C_pdT-T\left(\frac{\partial V}{\partial T}\right)_{p}dp
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Introduction
Equation
Latex Code
\left(\frac{\partial T}{\partial V}\right)_{S}=-\left(\frac{\partial p}{\partial S}\right)_{V}~,~~\left(\frac{\partial T}{\partial p}\right)_{S}=\left(\frac{\partial V}{\partial S}\right)_{p}~,~~ \left(\frac{\partial p}{\partial T}\right)_{V}=\left(\frac{\partial S}{\partial V}\right)_{T}~,~~\left(\frac{\partial V}{\partial T}\right)_{p}=-\left(\frac{\partial S}{\partial p}\right)_{T} \\ TdS=C_VdT+T\left(\frac{\partial p}{\partial T}\right)_{V}dV~~\mbox{and}~~TdS=C_pdT-T\left(\frac{\partial V}{\partial T}\right)_{p}dp
Explanation
Latex code for the State functions Maxwell Relations. I will briefly introduce the notations in this formulation. Absolute zero temperature cannot be reached by cooling through a finite number of steps.
- : Internal energy,
- : Enthalpy ,
- : Free energy,
- : Gibbs free energy,
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